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 Typical products of the Langhe > Langa Grappas

Langa Grappas

|story| |definition| |characteristics| |production| |The Romano Levi's Grappas|

Story Back to the start of the page

The first mentions of Piedmontese grappa are found in duty documents in 1443. In the past its name was not “grappa” but dialectally “branda”; the word “grappa” has become of common use only since last century; but certainly the above mentions place Piedmont among the most ancient producers of brandy. The high fiscal charge, this beverage was subjected to, gave Savoy family a fundamental support for war and state expenses. Unfortunately, this product took scarce benefits from the sub alpine state political and military successes, suffering laws and duties severity. Contrarily to the common thought in Piedmont, grappa was not only a villain tradition. Even though this product is based on the noblest vine grape peels (treated and processed still fresh together with the most precious musts) , alembic was a common tool both for the country people and for the aristocracy. Evidence of this is given by the intense correspondence between Count Cavour and his cellarer, and by some laws reserving many “grappa” privileges for the “Alessandrina” aristocracy. The Savoy had great interest for the grappa: Carlo Emanuele I conferred Orazio Senese the privilege of “boiling all sort of liquors in 1583, and forbade the manufacturing of grappa without the “Protomedico” (the health authority) consent in 1627. The severity of  laws and the high fiscal charge acted as a counterbalance to all this interest. A dense network of informers spied the illegal producers and the accusers could employ all sort of violence against the smugglers. The Piedmontese alembic men, who were as strong as their own land, did not give up and developed very significant technological innovations illegally. Among the many innovations: the Stemmer brothers’ machine, which allowed the constant marc distillation a century before the “disalcoholator” appeared; the steam-working Rocco’s alembic (1870) which allowed an agile cream of tartar extraction; Comboni’s Experimental Station in Asti (1900-1905), and the new theories about the marc distillation. It is not certain if the Piedmont-styled bain-marie alembic originated from these but nowadays it is undoubtedly one of the best for treating delicately the humid-but-not-dripping marc.

Definition Back to the start of the page

Legally, grappa is the brandy obtained from the distillation of fresh and fermented marc. Specifically, it is called mono-vine grappa the one obtained by distilling marc from only one type of grapes; it has a generic denomination if the grape variety which originated the marc is not declared. Nowadays, the word “grappa” is reserved for the marc distillate produced in Italy; the other countries are allowed to use denominations such as “marc brandy” or “marc distillate”. In Italy, the production of grappa is about 33 millions of bottles. The origin of this distillate looses itself in the medieval centuries; however, it was certainly born in the Northern Italianregions (there are arguments between Piedmont, Veneto and Friuli). The distillation has probably started between VIII and VI centuries B.C. in Mesopotamia; while the distillation, applied mainly to the wine to obtain brandy, is quoted by the alchemists only from XII century A.C. onward. The legend tells about a Roman legionary returned from Egypt (where he had filched a system of distillation) in I century A.C., who learned marc distillation techniques and employed them in his land in Friuli. The first production in Friuli is dated back to 511 B.C. by the historian Luigi Papo; the Burgundians (who shortly appeared in Cividale) applied their apple distillation techniques to the marc and for the first time obtained grappa. Later on in the Middle age (1451), there is a first reference  to grappa distillation; when  a “unum ferrum ad faciendam acquavitem” was inventoried among the well-known notary Ser Everardo da Cividale’s properties. The word “grappa” originates either from the German “shnaps” (which means brandy or distillate) or more likely from the Piedmontese “rapa” or the Lombard “grapa” (words referred to the marc). Grappa represents a quite wide and diversified interest as far as importance in all the Italian regions (where it takes some peculiar dialect names) is concerned.

Characteristics Back to the start of the page

The marketed grappa presents the following chemical average composition:

Water ( 40-60%)
Ethylic alcohol (38-68%)
Methylic alcohol (max 1 ml per 100 ml of anhydrous alcohol)
Superior alcohols (max 500 mg per 100 ml of anhydrous alcohol)
Esters (100-600 mg per 100 ml of anhydrous alcohol)
Aldehydes (100-200 mg per 100 ml of anhydrous alcohol)
Acids (50-1000 mg per 100 ml pf anhydrous alcohol)

Water derives from the humidity of the marc, from the steam utilized in distilling, and from the distilled water added in the phase for the reduction of alcohol content. Ethylic alcohol is fundamental constituent for the grappa and represents one of the parameters for business evaluation. It is an uncoloured, unpleasant-smelling, and burning-tasting liquor; it is mixed with water by contracting its volume. Moreover, it is a good solvent for substances such as resins, alkaloids, polyphenols and other colouring and aromatic substances. This characteristic is exploited for the aromatization and aging of the grappa. Methyl alcohol is a toxic component for human body. 1 ml per 100 ml of anhydrous alcohol is the maximum allowed by the law. Methyl alcohol increases with the ensilage and in case the marc is not correctly preserved. Superior alcohols are alcohols with more than two carbon atoms. The most important are: isoamyls, isopropylic, propylic and butanol n°2. Some of these are formed during the alcoholic fermentation; some during marc ensilage. Superior alcohols have a narcotic effect on human body (comparable to the ethylic alcohol). There is a very low quantity of these alcohols in the grappa, so that their effect is rather modest physiologically. Esters are very numerous and very important for their organoleptic effect. The ethyl acetate is the ester in the largest quantity; then the ethyl lactate, the ethyl caprilate, the ethyl propionate, the isoamyl acetate, the isobutyl acetate, the methyl acetate, etc. Aldehydes are represented mostly by the acetic aldehyde, but the isovalerianic aldehyde, the butyric, the hexyl, the acetal and the furfural are also present. Volatile acids in the grappa formed themselves during the alcoholic fermentation and the ensilage. The most important is the acetic acid, then the formic, the butyric, the lactic, the propionic, the isolvalerianic, the capronic, the enantic, the pelargonic, the caprylic and the capryc. The acids are beneficial for the organoleptic characteristics of the grappa (only if present in modest quantity). Aromatized and aged grappa also contains several substances such as: alkaloids, essential oils, tannins, polyphenols, etc. Moreover, the grappa on the market can be sweetened with sugar and coloured with caramel; thus, these products can be also considered as constituents.

Grappa classification

Conventionally, grappa is divided into four categories:

 1) Young Grappa: conserved in wood containers, where it perfected its characteristics (not enriched by components which are different than those used in the distillation).
 2) Aged Grappa: preserved in durmast, ash or different type of wood barrels for a more or less long period. It gained characteristics which are different than those of its birth.
 3) Aromatic Grappa: from a variety of grapes whose peculiar aroma is transmitted to the distillate (muscat grappa, malvasia grappa, etc.).
  4) Aromatized Grappa: obtained by soaking it with officinal plants, which give grappa a determined aroma (rue grappa, gentian grappa, etc.).

 Grappa organoleptic evaluation

 It is necessary a gustative, olfactory, and visual evaluation in order to completely examine the quality of the grappa. As far as the visual test is concerned, two aspects are considered: the limpidity and the colour tonality. Limpidity is a fundamental feature for a grappa on the market. Incidental glazings or dusty suspensions are index of a bad manufacture. The colour tonality gives a first indication on which category the grappa belongs. Young grappas are crystalline white; aged grappas have a variable colour (from white to yellowish white). Aromatized grappas have the colour of the infused plant pigment (i.e. rue grappas have greenish reflections, blueberry grappas have a purplish-red colour).

 The olfactory test is based on sensations about the volatile elements in the grappa. Their presence is so important that makes this organoleptic test phase difficult. Olfactory sensations derive from three groups of chemical compounds: aldehydes, esters and alcohols. Aldehydes give a herbal scent, which becomes a negative aspect if it overcomes a certain intensity. The most representative compounds (as far as quantity and perception threshold) are the acetaldehyde and the isovaleraldehyde. Esters give different sensations according to their molecular weight. A light solvent and fruity scent corresponds to the most volatile group; an exotic fruit scent corresponds to the molecular medium weight group; the high molecular weight esters give a oily, rancid, unpleasant sensation. The ethyl lactate gives a raspberry-reminding pleasant sensation (only if present in small concentrations). Superior alcohols give an alcoholic sensation. Within certain limits, they give grappa a typical and positive character.

 The gustative test is carried out by introducing in one’s mouth a small quantity of grappa (which is swallowed). Subsequently one will feel: an alcoholic sensation; the sweet, acid, bitter taste, and globally tactile sensations; finally, by opening your mouth and inhaling air you can analyze the gustative-olfactory sensations. Sweet, acid and bitter are tastes which are present in the grappa; the remaining gustative sensations are the tactile sensations. The sweet taste is given the grappa by the alcohols group and the saccharose (which legally can be added up to a maximum of 2%). The acid taste is given grappa by the volatile acids during the distillation. If present in small quantities, they will result pleasant. The bitter taste, if indistinctly tasted, indicates a high presence of butyric and propionic acids, and becomes a negative side (it creates disharmony). On the opposite, if the bitter taste is imperceptible, it will create a pleasant contrast with the sweet taste. The polyphenols ,extracted from the wood during the ageing, create a bitter but pleasant shade. The grappa taste is said “plan” if lacks of acidity; “dry” if scarce of sweet components; “short” if the gustative-tactile sensations fade out swiftly; “round” if there is good harmony between all the components. There are other types of organoleptic tests which can be practically applied. Grappa is often diluted in 40°C water and led to a lower content of alcohol (30-35°) before tasting. This process is useful to seek for incidental negative sides, but it is not very trustable. In fact, the dilution reduces all the constituents concentration and changes grappa peculiar balance. Another evaluation method consists of smelling the glass just emptied or smelling a small strip of blotting paper poured in the grappa. A traditionally employed method consists of pouring some grappa on your hand, which then is strongly rubbed and smelled. This method is employed to discover hidden elements but it is not useful to give a global opinion on the grappa. The most significant difference between grappa and wine is the alcoholic content (40-60° for the grappa, 10-20° for the wine). High concentrated alcohol cause the oral mucosa a burning sensation, which makes the other gustative components analysis difficult. Grappa is drunk differently than the wine: it is always consumed small-sipped between meals, so that the evaluation parameters are different. A final observation regards the best glass for tasting grappa: the “small tulip” or the “shorted INAO”. Different glass shapes, which concentrate or loose the scent, are certainly to avoid. Grappa is tasted at ambient temperature (18-20C°).

Grappa alterations

 Limpidity and colour alterations: glazing or suspensions. This negative side occurs when the grappa is diluted in calcium-salted water, which became insoluble (in a strongly alcoholic ambient). Suspensions may occur also when the alcoholic percentage reduction causes the higher molecular weight components insolubilisation. These negative sides can be eliminated either through a tight adjuvant or by filtering the stratus filtration or through a depurating and clarifying complex clarification.

Yellow colour
When the alembic or the other recipients give iron. The remedy consists of a clarification and a second distillation.

 Light Bluish colour
In this case the alembic gives copper salts. The remedy is the same of the precedent case.

 Olfaction alterations:

 Mould smell
When the distillation marcs are mould-affected.

 Acetous smell
This cause of this negative side is to be sought in acetic marcs or in an incorrect heads separation, so that the grappa contains strong quantities of ethyl acetate and acetaldehyde. The remedy consists of careful heads-separation re-distillation. 

 Rotten eggs smell
In this case the marcs received abnormal fermentations with sulphorate hydrogen and mercaptans production. Copper sulphate and re-distillation solve this problem

Gustative alterations:

Wood taste
This negative side occurs when the grappa receives too high tannins cessions or scarcely noble tannins following a too long ageing or in new or unsuitable-wooded barrels. The correction is a liquid gelatine clarification.

 Bitter taste
This alteration derives from a bad marc preservation, which leads to the formation of butyric and propyonic acid (not removed while distilling). A clarifying and depurating treatment and a re-distillation avoid the problem.

Acid taste
When the separation of the tail compounds was not correct. A calcium carbonate disacidification and a re-distillation are necessary.

 Other alcoholic alterations:

 Low alcohol content
The cause is probably a bad de-flame. It is solved through re-distillation.

 High acidity
It is due to the fact that the distilled marcs were acetic. Calcium carbonate disacidification and re-distillation are necessary.

 Methyl alcohol high content
This negative side is due to a bad marc preservation and to an imperfect rectification. The remedy is redistilling.   

Production Back to the start of the page

Grappa production technique entails several operations (from marc ensilage to bottling). All the phases of the grappa process are here analyzed and schematized.

Marc ensilage

Grappa industrial production takes place at least 5-6 months a year; thus the fresh marc can be distilled only for short periods; then, a remaining marc ensilage is necessary for the next production. Moreover, virgin and semi-fermented marcs must necessarily be ensilaged in order to allow the transformation of sugars into alcohol. Technically, fresh marc distillation gives a better grappa, for biochemical reactions (which not always produce quality compounds) take place after the ensilage. Marcs are ensilaged in concrete tanks or silos, in epoxy resin-covered iron containers, or in wood vats. These containers must be cleaned and be intact of moulds or soured organic substances. Marc ensilage takes place after the pressing operation; in fact, it can undergo such alterations that can compromise a good result (only a few hours from the must separation). Marc must be placed in layers in the containers and pressed as much as possible, so that air pockets do not happen. Moreover, superficial marc layers must be protected from air contact through the employment of plastic material cloths.

Distillation

 The most important phase in the production of grappa is the distillation. Numerous volatile components are present in the marc. The most quantitatively significant are water and alcohol. Distillation is a physical operation through which some substances are separated and transformed into steam; then re-condensed. The operation is carried out through heat (which vaporizes liquids) and cold (which re-condense them). At atmospheric pressure water boils at the temperature of 100°C, while ethylic alcohol boils at 78.4°C; as a consequence, boiling mixture-sprinkled vapours contain more alcohol than the mixture itself. A nearly 95% alcohol and 5% water (azeotropic m.) mixture boils at an inferior temperature than the alcohol; thus, the vapours of this composition will firstly sprinkle; as a consequence, a higher than 95° alcoholic content cannot result through distillation; it derives that there will still be water in the boiler when the alcohol will be transformed into steam and re-condensed. The distillate will have a alcoholic content superior to the originating mixture. The hydroalcoholic mixture boiling point is intermediate to the water and alcohol point. More alcohol the mixture will have, closer the boiling point will be to the latter one. The boiling temperature of the constant-composed hydroalcoholic solution will raise as this will leave alcohol. In this phase, it is important to concentrate the alcoholic vapours at the maximum before re-condensing them (so that the number of distillations will be reduced). A de-flamer is utilized. It is a cooling system placed on the distillatory. Historically, it has had various shapes (lens, sphere, or simply snake shaped). The physical phenomenon exploiting this machine is the different boiling temperature between water and alcohol. Specifically, various vapours are formed at a certain temperature; they begin their ascensional motion; when they touch the still-cold superior part, they condense and fall down in the mass; much more water than alcohol will condense among vapours; thus they (when out of the distillatory) will have an alcoholic content superior to that of the vapours formed in the boiler. This phenomenon would occur even without the de-flamer, but only in the initial moments; for ( once the distillation is going on) the boiler headpiece would warm up excessively and the alcoholic vapours could not condense as before. This machine is so important for  industrial plants that distiller vapours reach even 95° of alcohol content; thus, they do not need a second distillation. On the opposite, it is not necessary using these concentrations for crafts, for the objective is 50-60° (and the de-flamer is simply a humid cloth wetting the boiler cover). The alcoholmeter is employed to measure the alcoholic content. Besides the de-flamer, the equipment for carrying out the distillation consists of:

Heat source, which gives the liquid energy; for a craft, it consists of a gas burner (for it allows a good regulation of the quantity of heat to supply).

The Boiler, which contains the product to distil; this must be copper-made (except for this metal, sulphured tastes are allowed) or silver steel-made. This for materials such as iron and aluminium are not suitable; they are easily attacked by marc acids, and become difficult to clean when corroded (besides the fact that they have a relatively short life); moreover, the remaining attached to the side could decompose both during the plant inactivity period and during the distillation (producing compounds likely to alter the grappa organoleptic characteristics).

The Boiler Cover, called “headpiece”; it can be “plan” (if water flows on it, in order to have a better de-flame), frustum of cone or pear-shaped. When there is no other form of de-flame, it advisable that the boiler headpiece have a surface as large as possible; the vapours will then meet it for the most. Copper or silver steel are preferable both for the cover than for the boiler.

The Header, which connects the boiler cover to the cooler; for its construction, copper is  mostly utilized; in absence of the de-flamer, it is advisable that it be rather developed (with a wide section at the boiler juncture which narrows to the coil.

The Cooler, which condense the vapours produced; it consists of the coil and the recipient. The coil is copper-made; its length and diameter are functional to the boiler capacity and the water temperature. A metal different than copper can be used for the coil recipient; however, wood is not suitable, for it badly disperses the heat and leads to a higher water consume. Historically, this equipment has been called “alembic”; there is a difference if it is a continuous or discontinuous process. In the first case the marc continuously enters from above; it meets the steam which finishes it and deprives it of the volatile components; finally, it is removed from the machine through a Archimedean screw. This type of distiller is mainly reserved for industrial productions. Discontinuous distillers (more common in small and artisan firms) are divided into:

Steam Distiller

Bain-marie Distiller

Direct Flame Distiller

Steam distillers have a boiler (external to the alembic) producing steam and pushing it into small boilers, so that the marc expires. The bain-marie distiller features an inter-space (between the source of heat and the marc) in which a fluid (water or oil) is enclosed. This machine has the peculiarity of avoiding marc overheating, which may lead to the formation of furfural and other disgusting-tasting substances. Different direct flame distillers are used if the marc is still underwater or placed on a flyover grill. A basket with marks (which avoids them the contact with the bottom or the sides, and thus it avoids them the overheating) is placed on the underwater marc alembics. As far as the emerged marc distiller is concerned, the boiler is divided into two sections from a copper grill; the water is put in the inferior one, while the marc is placed in the superior section. Moreover, the hydroalcoholic steam undergoes a partial de-flame; it must go trough the spongy marc mass.

 Rectification

 Distillation would not cause many problems if marc volatile elements were exclusively water and alcohol. On the opposite, this raw material contains a multitude of volatile elements; if these pass to the grappa in moderate quantities, they will give finesse and peculiarity; if they overpass a certain limit, they will depreciate the grappa and make it harmful. Rectification is the operation through which precious and less precious substances are separated. Rectification occurs continuously in plate-columned industrial plants; but in artisan distillation, it is carried out by dividing the grappa into three fractions: heads, body, and tails. The heads are formed by volatile substances which boil at a temperature lower than the one of the ethylic alcohol. In discontinuous distillations, they represent the first fraction of liquid leaving the cooler. Most of the methyl alcohol and ethyl acetate (responsible for the acetous smell) go away if  the heads are perfectly separated. The heads (eliminated with the first fraction leaving the machine) may have an alcoholic content of 15-20°. The body or “core” is formed by compounds boiling between 78.4° and 100°. With no alterations these compounds do not harm the grappa but they are part of its typical fund. The body is the central fraction of the distillation process, and it is the most important; in fact, it contains the most of ethylic alcohol and the least percentage of undesirable substances. Besides the ethylic alcohol, other alcohols (such as ester and isovalerialdehyde) are contained in the body. The tails are formed by volatile constituents boiling at over 100° and gathering in the last part of the distillate. Distillation never reaches these temperatures; however, several of these chemical compounds are rather soluble in hot alcoholic vapours, and partially they are dragged even though they are not soluble in the same vapours. Acids (above all acetic acid, which gives grappa a sharp taste) must be separated carefully, for they can reach the distillate even though they do not boil at a temperature lower than 100°. Thus tails represent the third fraction of the distillate. The high boiling substances pollution starts just when the process temperature overcomes 90°. The more violent is the boiling, the higher it will be.

 Alcoholic content reduction

 The grappa obtained may have an alcoholic content of 50-60°. If it is not going to be aged, or if it is not going to be consumed with that content, the alcoholic content reduction is performed through water blending. Some charts indicate how many litres of water are necessary for the grappa to reach a certain temperature (i.e. 38.5 l of water give 100 l of grappa an alcoholic content of 40-55°). Some compounds soluble in alcohol-enriched mixtures insolubilaze (when alcoholic content-reduced), and become easily separable through a simple filtration or clarification. This is an advantage for the stability of the grappa in time, for it eliminates big quantities of acids (such as myristic, laurylic, stearic, oleic, linoleic, linolenic and esters formed with ethylic, methyl and amyl alcohol, and hydrolazying acetal). The water added to obtain the alcoholic content reduction must not be hard; in fact, if it contained salts which are hardly-soluble in an alcoholic ambient, these would compromise the stability and originate deposits and turbidity easily. The law enforces the utilization of distilled water.

Clarification

This operation (together with the cooling and filtration) helps eliminating the distillate negative sides; these originate after the various components insolubilization, and make the grappa turbid. The operation may present negative sides which must be eliminated. Organic or mineral products are employed in the clarification; once suspended in the water, they slowly enter the distillate and flocculate (dragging impurities to the bottom). The treatment is very efficient but it must be considered that the products used remove also big quantities of scents, depreciating the treated grappa.

Cooling

This phase facilitates fusel-oils insolubilization, so that they can be separated through filtration. The grappa is led to a temperature of 10-20° for at least 48 hours; then it is filtered with separators holding the insolubilized oils.

 Filtration

 It makes the grappa limpid by holding the clarifying not-precipitating floccula and other incidentally-present suspended substances. Filtration is carried out through paper or pressure filters (which employ filtration adjuvants) or through pre-formed filtrating strata. Generally, low-medium permeability strata are needed to obtain a good quality filtrate.

 Ageing

 Ageing a distillate means preserving it in wood barrels (which have not been proofed) for a certain time. Aged grappas are a big category among grappas; ageing is an unquestionable way used by the producer to attest his skills in producing quality marc brandy. There are a short (small) and a long (big) period of ageing for the grappa. Basically, the small ageing is a sort of wood refining; in fact its duration is 6-12 months, barrel cessions are minimum, and the barrels can be of different sizes and reach over 6000 litres of capacity. This way the grappa becomes straw-yellow coloured or remains white coloured, its taste harmonize itself and the scents slightly increase in intensity and fineness. On the contrary, the big ageing lets the grappa stay in small barrels (700 litres) for 5-15 years. In this case the grappa obtained is completely different from the distillate introduced in the barrels; its colour is between straw-yellow and golden, its smell becomes more fragrant and intense, and its taste becomes round with a slight sensation of vanilla. Ageing will produce the expected organoleptic characteristics only if three factors will be respected:

Pleasant substances cession from the wood

Distillate oxygenation

A right period of staying in the recipient

The wood releases determined poliphenolic compounds (i.e. quercin, quarecitrin, and other terms conferring the classic organoleptic structure). The wood also releases hemicellulose and lignin which hydrolyze and transform into sugars (pleasantly softening the taste). As far as this aspect is concerned, ash and cherry wood give optimum results (besides durmast wood, which is the most employed in barrel constructing). Although many firms add wood shavings or specific chemical substances, the result is never as good as the one obtained by ageing the grappa in wood bottles. Another important factor in grappa ageing is oxygenation. The oxygen, meeting the distillate, comes from the air through the wood pores; moreover, the grappa, which is out of the barrel, goes into the wood pores and is finely divided before meeting the oxygen; this results in a wide exchange surface which facilitates ethylic and superior alcohols oxidation reactions. This oxidation leads to the formation of organic acids; they react to alcohols and create esters, which give fundamental characteristics to the grappa bouquet. The third indispensable factor for the ageing is the time spent by the distillate in the wood. Chemical phenomena, which originate new qualitatively-important compounds, are very slow; thus it is necessary waiting for very long periods (i.e. 10 years) for these reactions to occur. Time can be reduced by employing inferior capacity barrels, more pored or newer woods, which are not finished by precedent distillates yet. These techniques are not utilizable over a certain level; the risk is compromising the aged grappa elegance, fineness, and harmony. Barrels construction needs to follow some rules, for it is indispensable that barrels have some characteristics. First of all (once cut and reduced in boards the durmast, cherry or ash trees) it is necessary for these boards to stay in airy rooms for at least 3-4 years, so that the wood can dry; this operation is important, since most of the astringent and bitter poliphenols oxydate and transform into more pleasant tannins. Moreover, it is important that barrel construction staves be extracted by cleaving and not sawing the wood; this to avoid a too high porosity which would imply strong losses for the distillate through evaporation. Before employing the new barrels, they must be vaporized or carefully washed with hot water; this to eliminate the easily-soluble (but unpleasant for the distillate) wood substances; for this reason, it is advisable (before utilizing them for a big ageing of a quality grappa) to fill the barrels with a less precious brandy for 4-5 months. Moreover, when constructing small barrels, it is indispensable to employ very thick staves, so that volume losses for the distillate  and a too pushed oxygenation will not occur. Ageing rooms must be at medium temperatures (20-25°C) and have a relative humidity not lower than 70%. If they are too cold, the chemical reactions of the ageing will slow; if they are too hot, there will be a significant loss of grappa due to evaporation; if they are too dry, there is also a loss of volume. On the contrary, the alcoholic content decreases more easily in humid cellars; this for the alcohol is more volatile than the water, and humidity contrasts water but not alcohol evaporation.

 Bottling

 After verifying the ageing grade (probably through tasting) the grappa is confectioned in specific bottle; they have a capacity between 3 cl (mignon) and 2 l. Preferably they must be glass bottles, for glass well preserves the organoleptic characteristics of the grappa.

 Aromatized grappa and its production methods

 Aromatized grappas are a very important part among marc distillates; this for grappas gain the therapeutic virtues from the officinal plants utilized (besides assuming pleasant organoleptic qualities). Herb chemical substances, which can be slolubilized by the hydroalcoholic mixture, are divided into:

 Sugars, which therapeutically have intestine-regulating properties and exercise an energetic action on the system

 Organic acids, which are mostly the malic, oxalic, citric, succinic, and tartaric.

 Phenols, which are tannins, anthraquinones, and florogulucinics; their therapeutic properties are an astringent, and laxative action.

 Triterpenic saponins, which facilitate diuresis, expectoration, and perspiration.

 Steroids, which consist of glycosides and steroid saponins: the first utilized to cure decompensation, the latter have similar effects to the ones of triterpenic saponins.

 Alkaloids, which stimulate respiration, increase perspiration and salivation, and act variously on the nervous, digestive, and cardio-circulatory system.

Essences, which are very important from an organoleptic point of view.

Resins, which carry out important functions for the respiratory and digestive system.

Aromatized grappa preparation can be performed in two ways: by adding herbs as alcoholic dye, or through the maceration of an officinal plant (fresh or dried) in the grappa. The officinal herb alcoholic dye is prepared by letting the herbs macerating in content-determined alcohol for a period of 5-10 days. Generally, five parts of alcohol per each part of officinal herb are employed. At the expiring-date, solid parts are separated from the liquid phase through filtration or pressing; the alcoholic dye obtained will be added to the grappa; legally, dye-added alcohol mustn’t be higher than the 3% of the one in the grappa. This type of preparation is useful for it allows grappa aromatization; and it always starts from the same base. Moreover, this type of process allows the choice of the optimal aromatization grade. The direct maceration of officinal plants in the grappa is carried out by immerging the herbs in the grappa (already alcohol-contented for the marketing). Maceration time varies according to the officinal plant utilized and the grappa alcohol content (the higher the alcohol content is, the stronger the solvent effect will be, the lesser time will take). The maceration period must end when the brandy has extracted the good aromatic principles (but not the unpleasant ones). Thus, it is not advisable to leave the herbs in the grappa until it is consumed. Qualitatively speaking, there is not very much difference between using a fresh or dried plant; undoubtedly, the second system is more convenient, for every herb is easily available at the herbalist’s shop. An amount of sugar is always added in aromatized grappas, for it betters their taste and makes it more harmonic. Legally, a 2% maximum addition is allowed; if home-made a maximum of 5-6% can be added; if this component will increase, the grappa will be closer to a liquor. The grappa for the preparation must be a good quality one; in fact, it is a mistake utilizing a poor quality grappa; its taste will not be hidden by the aromatization; generally, unpleasant-tasting combinations originate. Moreover, it is to be considered that diluting an aromatized grappa is dangerous, for some components may insolubilize and cause turbidity; some alterations in the taste harmony may also occur. At the end of the aromatization it is always advisable filtering the brandy.

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